Molar volume means that 1 mol of any gas occupies a volume of 22.4 L at standard temperature and pressure conditions. the molar mass of Ar is 40 g/mol this means that a mass of 40 g occupies a volume of 22.4 L therefore a mass of 120 g of Ar occupies a volume of - 22.4 L / 40 x 120 therefore volume occupied by Ar - 67.2 L