Experience in _____ certain systems, such as erp and scm systems, can teach the it staff for how many minutes or seconds per year the system is likely to fail.
Experience in operating certain systems, such as erp and scm systems, can teach the it staff for how many minutes or seconds per year the system is likely to fail. If you are looking for the verb you need to use here, then it is the word operate. You operate a system, which means that you work in it.
